LTCPAA

Long Term Measurements of Chemical and Physical Properties of Atmospheric Aerosol at Dome C

LTCPAA

© PNRA

Progetto

Questo progetto prevede l’installazione di un laboratorio che permetta di effettuare misure a lungo termine delle proprietà chimiche e fisiche dell’aerosol atmosferico a Dome C. Questo tipo di misure è fondamentale per comprendere meglio le sorgenti attuali del particolato e dei gas atmosferici, i loro processi di trasporto a lungo raggio, i loro meccanismi deposizionali e post-deposizionali, e la loro trasformazione chimica. L’ottenimento di un data set sufficientemente ampio è basilare sia per la comprensione delle variabili che influenzano il clima odierno, sia per una corretta interpretazione dei record paleoambientali da carote di ghiaccio, oltre che per la calibrazione dei modelli previsionali.

Oltre allo studio delle proprietà fisiche e chimiche dell’aerosol e dei gas atmosferici come l’ozono, è anche continuamente misurato il flusso di raggi cosmici per lo studio dell’attività solare e della precipitazione delle particelle ad alta energia.

Project

This project has main target the installation of a laboratory that allows to carry out long-term measurements of the chemical and physical properties of atmospheric aerosol at Dome C. This kind of measurement is fundamental to better understand the current sources of particulate matter and atmospheric gases, their long-range transport processes, their depositional and post-depositional mechanisms, and their chemical transformation. The achievement of a sufficiently large data set is fundamental both for understanding the variables that influence today's climate and for a correct interpretation of paleo-environmental records from ice cores, as well as for the calibration of predictive models.

Besides the study of the chemical and physical properties of atmospheric aerosol and gaseous as ozone, it is also measured continuously the cosmic ray flux for the study of the solar activity and the precipitation of high energy particles.

Scientific Objectives

  • understanding the climate-aerosol feedback processes in regions that are very sensitive to environmental and climatic changes;
  • establishing the background values of the atmospheric load, size distribution and chemical composition of aerosol;
  • improving the reliability of climatic models by making available a long-term data set for a more effective evaluation of the forcings exerted by global aerosol (ERFari and ERFaci);
  • studying, with sufficient statistics, the seasonal and inter-annual trend of the concentrations of key-components of aerosol (S-, N- and C-cycle compounds; biogenic emissions; dust; sea spray);
  • evaluating the present source strength and long-range atmospheric transport efficiency of aerosol produced in the marine and continental areas at lower latitudes;
  • estimating the contribution of aerosol sources to Antarctica from local to regional scale;
  • studying the effects of photochemistry and radical sources (ozone) on chemical reactions of gaseous aerosol precursors and New Particles Formation in very peculiar (temperature, continuous summer irradiance) atmospheric conditions;
  • improving the reliability of paleo-climatic and paleo-environmental reconstructions by ice core stratigraphies, also by a better knowledge of the aerosol- snow surface interchange;
  • evaluating the possible role of cosmic rays in New Particle Formation (NPF) in an area where nucleation is unlikely due to low atmospheric concentrations of aerosol precursors.

Research Activities

Dome C

Dome C site (75°06′S, 123°21′E) is located at 3233 m a.s.l. on the East Antarctic plateau south of the Indian Ocean, about 1100 km from the coastline. Located on the top of a large dome with negligible slope, Dome C is not affected by the typical intense katabatic winds observed in Antarctica. The thickness of the ice cap is 3250±25 m, has a mean annual temperature of −53°C and a mean annual accumulation rate of some tens of mm of equivalent water (corresponding to about 7.4 cm of snow) per year at the surface. This small accumulation rate is due to the very low humidity in the atmosphere.

Dome C represents a strategic place for these studies, thanks to the remote location of the site, which is characterized by very low levels of contamination (both for the distance of the major sources of particulate and the high altitude, besides the isolation due to the establish of the winter polar vortex) and the proximity to the minimum of the geomagnetic field, which allow to measure a cosmic ray flux relatively high.

Shelters

Surface snow (roughly 1 cm depth) is collected in a dedicated area, called "CLEAN AREA", 200 m far from ATMOS shelter
The ATMOS shelter is located at about 700 m away from Concordia Base, in an upwind position with respect to the prevailing winds, in order to minimize contamination from Base’s emissions. The shelter is devoted to all the chemical and glaciological experiments
The PHYSIC shelter is located at about 600 m away from Concordia Station. The shelter is devoted to all the physical experiments

Instruments

Daily automatic low-volume PM10 aerosol
4-stage inertial impactor size-segregated aerosol
Bulk low-volume PM10 aerosol
Bulk medium-volume PM10 aerosol
Bulk high-volume PM10 aerosol
Ozone analyzer
DMPS (Differential Mobility Particle Sizer)
Nephelometer
PSAP (Particle Soot Absorption Photometer)
OPS (Optical Particle Sizer)
CIC (Cluster ion counter)
Muon Counter (AMiCO)
Neutron Counter

About Us

Principal Investigator:
Prof. Rita Traversi - rita.traversi@unifi.it

Unit Responsible: Prof. Rita Traversi (University of Florence – traversi@unifi.it)

University of Florence (Silvia Becagli, Mirko Severi, Laura Caiazzo – currently INFN Florence, Alessandra Amore, Raffaello Nardin, Rita Traversi)

  • Set up of an array of sampling and measurement devices to be used for long-term studies (bulk PM10 at low and medium vol., 4-stage impactors)
  • Devoted chemical analyses (ion content, major and trace metals, EC/OC) on continuously collected aerosol and snow samples

 

INFN Florence (National Institute of Nuclear Physics) and Department of Physics and Astronomy, University of Florence (Lorenzo Bonechi, Raffaello d’Alessandro)

  • Continuous measurement of Cosmic Ray flux by Muon Counter (AMiCO) to study possible correlations with the rate of production of particulate matter and atmospheric conditions

 

University of Oulu – Finland (FINNARP and Academy of Finland Project: CRIPA – “Cosmic Rays In Polar Atmosphere” – PI: Prof. Ilya Usoskin, Stepan Poluianov)

  • Continuous measurement of Cosmic Ray flux variability in the high-elevation polar atmosphere and study of their effects by 2 Neutron Monitors

Unit Responsible: Dr. Paolo Cristofanelli (CNR-ISAC Bologna– paolo.cristofanelli@isac.cnr.it)

CNR-ISAC Bologna (Paolo Cristofanelli, Davide Putero, Francesco Calzolari, Maurizio Busetto)

  • Investigation of the variability of near-surface ozone and aerosol physical properties (absorption and scattering coefficient, size distribution) in the continental Antarctic PBL
  • Related performing of QA/QC actions to assure the quality of recorded data

 

CNR-IIA, Rome (A. Ianniello, F. Vichi, G. Esposito, M. Frattoni, A. Imperiali)

  • Summer campaigns of sampling and analysis of VOCs and gas/particulate repartition for N-cycle species

 

FMI (Finnish Meteorological Institute) and UHEL (University of Helsinki) – Finland (Aki Virkkula, John Backman, Pasi Aalto)

  • Continuous measurements of size distribution, light scattering and absorption measurements, cluster ion counting

Unit Responsible: Prof. Andrea Gambaro (University of Ca’ Foscari, Venice – gambaro@unive.it)

University of Ca’ Foscari, Venice (Andrea Gambaro, Elena Barbaro, Matteo Feltracco)

  • Summer campaigns of PM10 aerosol sampling and analysis of a number of species: 40 free L- and D- amino acids, 7 monosaccharides (arabinose, fructose, galactose, glucose, mannose, ribose, xylose), 8 alcohol-sugars (arabitol, erythritol, mannitol, ribitol, sorbitol, xylitol, galactitol, maltitol), 3 anhydrosugars (levoglucosan, mannosan and galactosan), sucrose, 11 phenolic compounds (PC) (vanillic acid, isovanillic acid, homovanillic acid, vanillin, syringic acid, syringaldehyde, p-coumaric acid, coniferaldehyde, acetosyringone, acetovanillone and ferrulic acid)

Unit Responsible: Prof. Marco Grotti (University of Genova – grotti@unige.it)

University of Genova (Marco Grotti, Francisco Ardini)

  • Elemental and isotopic analysis of PM10 aerosol and snow samples (in collaboration with SIDDARTA project)

Metadata

Kind of Sampling Location From (date) To (date) Resolution Time Type of Measurement Research Unit (RU)
Skypost PM10 ATMOS shelter 05/12/2016 Currently ongoing Daily Bulk PM10 by low-volume sampler devoted to the analysis of chemical ionic markers RU 1 - University of Florence
Dekati-4 ATMOS shelter 05/12/2016 Currently ongoing 4 days Size-segregated aerosol by 4-stage inertial impactor by low-volume sampler devoted to the analysis of ionic markers and major metals RU 1 - University of Florence
PM10 ECHO-PM ATMOS shelter 13/12/2016 Currently ongoing 8 days Bulk PM10 by low-volume sampler devoted to the measurements of Elemental and Organic Carbon RU 1 - University of Florence
PM10 ECHO-PUF ATMOS shelter 28/01/2017 Currently ongoing 32 days Bulk PM10 by medium-volume sampler devoted to the determination of main and trace metals by ICP-MS and PIXE techniques RU 1 - University of Florence / RU 4 - University of Genova
Surface Snow Clean Area 05/12/2016 Currently ongoing 2 days Measurements devoted to the analysis of chemical ionic markers RU 1 - University of Florence
Muon Counter (AMiCO) PHYSIC shelter 23/12/2017 Currently ongoing 1 minute Continuous monitoring of the charged cosmic rays intensity RU 1 - INFN of Florence
Neutron Counter PHYSIC shelter December 2014 Currently ongoing 1 minute Cosmic Ray Flux measurements RU 1 - University of Oulu
Ozone analyzer ATMOS shelter December 2016 Currently ongoing 1 minute Measurements of variability of near-surface ozone RU 2 - CNR-ISAC of Bologna
DMPS ATMOS shelter December 2007 Currently ongoing 13 minutes Differential Mobility Particle Sizer: measurements of particle size distribution in the 10 - 1000 nm size range RU 2 - FMI and UHEL of Helsinki
OPS ATMOS shelter December 2007 Currently ongoing 10 minutes Optical Particle Sizer: measurements of particle size distribution in the 0.3 - 10 nm RU 2 - FMI and UHEL of Helsinki
Nephelometer ATMOS shelter December 2007 Currently ongoing 3 seconds Measurements of scattering e backscattering radiation at 3 wavelengths RU 2 - FMI and UHEL of Helsinki
PSAP ATMOS shelter December 2007 Currently ongoing 1 second Particle Soot Absorption Photometer: Measurements of absorption at 3 wavelengths (660, 530, 467 nm) RU 2 - FMI and UHEL of Helsinki
CIC ATMOS shelter December 2018 Currently ongoing 1 second Cluster ion counter: measurements of ion size distributions in the sub 1 nm to about 3 nm RU 2 - FMI and UHEL of Helsinki
HV-PM10 Roof of ATMOS shelter 2016-2017, 2017-2018, 2018-2019, 2019-2020 summer campaigns Currently ongoing during summer 10 days Multi-stage high volume impactor devoted to the analysis of phenolic compounds, free amino acids and sugars RU 3 - University Ca' Foscari of Venice
Surface Snow Clean Area December 2016 Currently ongoing 30 days Measurements devoted to the analysis of isotopic analysis by ICP-AES, ICP-QMS or ICP-SF-MS RU 4 - University of Genova

Summer Campaigns

2016/2017 Summer Campaing:

  • Equipping a new laboratory in the "ATMOS" shelter with several sampling and measurement devices:
    • 1 Skypost for daily PM10 sampling
    • 1 ECHO-PM for the 4-stage impactor Dekati-4, with 4-day resolution
    • 2 ECHO-PUF for the metal sampling, with 32-day resolution
    • 1 ECHO-PM for EC-OC, elementary and organic carbon, sampling, with 8-day resolution
    • 1 ECHO-PM for the daily NO3- sampling, lasted only 4 months in total, during the summer campaign and the first period of the winter campaign
    • 1 high-volume sampler for halogen sampling, during the summer campaign
    • ozone analyser
    • a meteorological trigger with an anemometer on the roof, to prevent possible influences of the Base
  • Holing the wooden plates on the roof of the shelter, insulating them with the rockwool panels, and allowing the passage of the metal pipes and temperature probes connecting samplers (inside the shelter) to the cut-off heads (on the roof)
  • Putting on wooden panels the aspiration pumps, in order to dampen vibrations and related noise
  • Building specific housings (by wood and polyethylene plates) to prevent snow accumulation on the sampling head on the roof
  • Carrying out maintenance and instrument intercomparisons of continuous size distribution measurements:
    • nephelometer
    • DMPS
    • OPS
    • PSAP
  • Starting with superficial snow samples collected in the “clean area”

2017/2018 Summer Campaing:

  • Prosecution of the atmospheric and superficial snow sampling
  • Halogen sampling with a high-volume sampler during the summer campaign
  • Atmospheric measurements of the largest portion of the organic fraction (VOC, aldehydes, carboxylic acids) during summer period
  • Installing of a new anemometer and trigger
  • Installing of the muon counter
  • Intercomparison of PSAP system with a similar system calibrated
  • Checking of DMPS performances by intercomparison with a portable CPC (Condensation Particle Counter)
  • Packing of all the samples at -20°C ready for shipping to Italy
  • Training to the new winterover personnel

2018/2019 Summer Campaign:

  • Prosecution of the atmospheric and superficial snow sampling
  • Annual checking and maintenance of all the instrumental set: atmospheric aerosol samplers, aspiration pumps, particle counters and ozone analyser
  • Atmospheric measurements of the largest portion of the organic fraction (VOC, aldehydes, carboxylic acids) during summer period
  • Substitution of all the cables of the high-volume sampler and starting of the halogen sampling during summer period
  • Back-up of all the data registered during the previous winter period
  • Rearrangement of the anemometer on the roof of the shelter and changing the set-up of the trigger program for stopping the pumps
  • Reorganization of the rooms inside ATMOS shelter
  • Removal of the wooden housing on the roof
  • Replacing of the PSAP instrument with a less noisy one
  • Installation of the Cluster Ion Counter (CIC)
  • Packing of all the samples at -20°C ready for shipping to Italy
  • Training to the new winterover personnel

2019/2020 Summer Campaign:

  • Prosecution of the atmospheric and superficial snow sampling
  • Annual checking and maintenance of all the instrumental set: atmospheric aerosol samplers, aspiration pumps, particle counters, ozone analyser, and neutron and muon counters
  • Halogen sampling with a high-volume sampler during the summer campaign
  • Back-up of all the data registered during the previous winter period
  • Substitution of the connection cable of the anemometer and of the relays of the meteorological trigger
  • Adding of some function in the trigger’s program
  • Packing and sending back to Italy the Skypost and substitution with a new automatic PM10 sampler (Giano DadoLab)
  • Packing of all the samples at -20°C ready for shipping to Italy
  • Training to the new winterover personnel

Collaborations

INTERNATIONAL COLLABORATIONS AND SCIENTISTS INVOLVED

  • IGE (Grenoble, France). Dr. J. Savarino – N-species sources and air/snow processes; Dr. M. Legrand – biogenic S compounds; Dr. B. Jourdain – sea spray aerosol
  • KOPRI (Incheon, South Korea). Dr. Y.J. Yoon. Comparison of aerosol chemical and physical properties with other Antarctic sites, King Sejong Station and Jang Bogo Station
  • Institute of Alpine and Arctic Research (INSTAAR); University of Colorado (Boulder, USA). Dr. D. Helmig: N-cycle compounds at DC and comparison South Pole – DC aerosol
  • Desert Research Institute (Reno, Nevada). Prof. J. McConnell: comparison South Pole – DC aerosol and ice core stratigraphies study
  • University of Ghent (Ghent, Belgium). Prof. F. Vanhaecke. Pb, Sr and Nd isotopic ratio by multi-collector ICP-MS measurements
  • Sodankylä Geophys. Obs. (Sodankylä, Finland), University of Oulu. Prof. I.G. Usoskin, Dr. S. Poluianov: Cosmic Rays monitoring
  • FMI (Helsinki, Finland). Dr. A. Virkkula. Continuous size distribution measurements by OPC and DMPS
  • Joint Antarctic Research Institute (Wellington, NZ). Prof. N. Bertler: geochemical cycles, mineral dust source areas and ice core records.
  • EMPA (CH). Dr. C. Zelwegger: World calibration Center Surface O3

COLLABORATIONS ON FIELD

  • Personnel of SIDDARTA project (P.I. Silvia Nava)
  • Personnel of BrHgSnow project (P.I. Andrea Spolaor)
  • Personnel of BSRN project (P.I. Angelo Lupi)

Publications

Poluianov, S.V., I.G. Usoskin, A.L. Mishev, et al., GLE and Sub-GLE Redefinition in the Light of High- Altitude Polar Neutron Monitors, Solar Phys., 292, 176, 2017, doi: 10.1007/s11207-017-1202-4.

Poluianov, S., I. Usoskin, A. Mishev, et al. Revisited definition of GLE, Proc. Sci. (ICRC2017), Proc. 35rd Internat. Cosmic Ray Conf., Busan, 125, 2017.

Cristofanelli et al., Analysis of multi-year near-surface ozone observations at the WMO/GAW “Concordia” station (75°06′S, 123°20′E, 3280 m a.s.l. – Antarctica), Atmospheric Environment, 177, 54-63, 2018.

Mishev, A.L., I.G. Usoskin, Assessment of the radiation environment at commercial jet-flight altitudes during GLE 72 on 10 September 2017 using neutron monitor data, Space Weather, 16, 1921-1929, 2018, doi: 10.1029/2018SW001946.

Gil, A., G.A. Kovaltsov, V.V. Mikhailov, A. Mishev, S. Poluianov and I.G. Usoskin, An Anisotropic Cosmic-Ray Enhancement Event on 07-June-2015: A Possible Origin, Solar Phys., 293, 154, 2018, doi: 10.1007/s11207-018-1375-5.

Mishev, A., I. Usoskin, O. Raukunen, M. Paassilta, E. Valtonen, L. Kocharov, R. Vainio, First Analysis of Ground-Level Enhancement (GLE) 72 on 10 September 2017: Spectral and Anisotropy Characteristics, Solar Phys., 293, 136, 2018, doi: 10.1007/s11207-018-1354-x.

Mishev, A., I. Usoskin, Analysis of sub-GLE and GLE events using NM data: space weather applications, J. of Phys.: Conf. Series, 1, 1181, 2019, doi: 10.1088/1742-6596/1181/1/012006.

Conference Contributions

Traversi, R., S. Becagli, L. Caiazzo, M. Busetto, F. Calzolari, P. Cristofanelli, B. Petkov, M. Severi. Composizione chimica dell’aerosol atmosferico e della neve superficiale a Dome C (Antartide Orientale) risultati da 10 anni di attività. ORAL. “VIII Convegno Nazionale sul Particolato Atmosferico” PM2018 – 23-25 Maggio 2018, Matera.

Becagli, S., R. Traversi, M. Severi, L. Caiazzo, L. Lazzara, G. Mori, C. Marchese, C. Scarchilli, V. Ciardini. Aerosol biogenico in Antartide centrale. Deduzioni sulle interazioni oceano-atmosfera. ORAL. “VIII Convegno Nazionale sul Particolato Atmosferico” PM2018 – 23-25 Maggio 2018, Matera.

Traversi, R., S. Becagli, L. Caiazzo, M. Busetto, F. Calzolari, P. Cristofanelli, B. Petkov, M. Severi. Aerosol and Surface Snow Chemical Composition at Dome C from 10-yr Long Records. ORAL. “A SCAR & IASC Conference” Polar2018 – 15-26 June 2018, Davos.

Becagli, S., R. Traversi, M. Severi, L. Caiazzo, L. Lazzara, G. Mori, C. Marchese, C. Scarchilli, V. Ciardini. Biogenic Aerosol in Central Antarctica: The Ocean-atmosphere Interaction. POSTER. “A SCAR & IASC Conference” Polar2018 – 15-26 June 2018, Davos.

Virkkula, A., V.-M. Kerminen, T.Petäjä, G. De Leeuw, E. Asmi, D. Brus, T. Laurila, H. Timonen, K. Teinilä, E. Rodriquez, J. Svensson, V. Aaltonen, J. Backman, R. Hillamo, M. Sipilä, T. Jokinen, E. Järvinen, T. Nieminen, R. Väänänen, H. Manninen, X. Chen, P.P. Aalto, H. Grythe, M. Busetto, C. Lanconelli, A. Lupi, V. Vitale, R. Weller, A.C. Saulo, and M. Kulmala: Final results of a project on Antarctic aerosols in 2013 -2016. Proceedings of the NOSA-FAAR Symposium 2018, Report Series in Aerosol Science, 208, 134 (http://www.atm.helsinki.fi/FAAR/reportseries/rs-208.pdf), 2018.

Virkkula, A., Grythe, H., Backman, J., Aalto, P.P, Petäjä, T., Busetto, M., Lupi, A., Vitale, V., Udisti, R., Becagli, S., Sheridan, P., Ogren, J., and Kulmala, M.: Surface Aerosols at Dome C and Comparison with Observations at the South Pole, Abstract nr. 2499. “A SCAR & IASC Conference” Polar2018 – 15-26 June 2018, Davos.

Traversi, R., S. Becagli, L. Caiazzo, M. Busetto, F. Calzolari, P. Cristofanelli, B. Petkov, M. Severi. KEYNOTE. Chemical composition of atmospheric aerosol and surface snow at Dome C (East Antarctic Ice Sheet): an overview from 10-yr long records. “XXVII Congresso della Divisione di Chimica Analitica” – 16-20 Settembre 2018, Bologna, Italy.

Becagli, S., R. Traversi, M. Severi, L. Caiazzo, L. Lazzara, C. Marchese. Insight on the Ocean- Atmosphere interaction in polar Southern Emisphere by long term aerosol measurements in Central Antarctica. POSTER. “XXVII Congresso della Divisione di Chimica Analitica” – 16-20 Settembre 2018, Bologna, Italy.

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Feng Zhang and Ancestor Xie Lu also had worried expressions on their faces.The bloody head Regen CBD Gummies Official Website: Explore the Benefits and Reviews Seeing Platinum Keto ACV Gummies Review: Unlocking the Power of Keto and ACV for Optimal Weight Loss and We this scene, the faces of the leader of the Blood Hand Sect and others changed drastically, and they looked at Feng Zhang with an extremely unkind look Especially the leader of the Blood Hand Sect, he yelled angrily Xue Tu, this trash He also didn t expect that Xue Tu, who was at the peak of the Golden Elixir stage, would be killed by Feng Zhang, who was at the late stage of the Golden Elixir stage, and that was just A Natural Bliss Gummies for Erectile Dysfunction: A Comprehensive Guide to Relief (hTQEn) sword is simply useless Later, what Hong Meng, the leader of the Blood Hand Sect, did not expect even more was that Feng Zhang was so invincible that he killed several Golden Core disciples of the Blood Hand Sect one after another There are even two who are at the peak of the Golden Core stage A divine sword from the heavens, wielded with great proficiency and extremely miraculous After all, the Cangshan Sect s techniques had an extraordinary origin, coming from the later unfathomable Fairy Feng Potian and Luoyue and others.

He was really arrogant If there was no background, how could he have such courage However, the traces of his actions from Lu Yu were unable to tell which family s descendant he was Procana CBD Ultra 1500mg Reviews: A Comprehensive Analysis of Efficacy and User Satisfaction (ZFtec) from.Is it really reliable In fact, how could a person like He Zhenlong take Lu Ziji in just because he doted on his little daughter He Yan er Heshenghua Sect, Thousand Blades Sect, and Scarlet Flame Tiger Zhao Family, the three top immortal cultivating forces, immediately fell out He even directly said that Lu Ziji was his son in law and He Yan er s consort The biggest reason is here Five hundred years ago, the fifth grade Vermillion Bird Sacred Tree suddenly shook, the tree bleeds, and even withered a little He Wenxin and He Zhenlong both felt that this was an ominous sign, but they could not calculate the secret.

Yan Xunnan was still frightened when she saw this scene.com But now, I, who was originally on the road to invincibility, have been forced to such an extent by a mere ant in the foundation building stage.

In the past few months, Lu Yu had gained nothing about the whereabouts of Fairy Feng Potian Luoyue and others, and why the Cangshan Sect had expelled them to settle in such a poor place as Zhangzhou.It was this Purple Blood Ganoderma that caused the death of more than 1,300 people in the banker Lu Yu took it and flicked it casually, and the forbidden words on the ancient box cracked and shattered.

Lu Yu, the person who destroyed Lord Ye Tianzhen and others, has arrived at Cangshan Star at this time A bunch of purple gold rainbow, like tearing apart the heaven and earth, passes through the space channel of Tatian Road between Emperor Star and Cangshan Star.He will be hunted down all day long Although the Liuyan Fantasy Pearl in Lu Yu Revive CBD Gummies Reviews Consumer Reports: A Comprehensive Guide to CBD Gummies s hand is also a cave treasure, it has Revolutionize Your Weight Loss Journey with Keto ACV Gummies 7500mg: A Game-Changing Supplement for not been cultivated well and has insufficient foundation.

The soul is gone Wuwei Temple s body refining method has always been the most powerful in the world of Cangshan Xingxiu.With Exploring the Benefits of Penguin CBD Gummies for Natural Wellness and Pain Relief the Wind and Thunder Divine Seal, Pengyun Zhenjun could never imagine Transform Your Body with Simply Lean Keto Gummies: A Game-Changing Weight Loss Solution that the Emperor s Constellation Star could still break through What is CBD Gummies and How Do They Work? Find Out in 2025! the defense Looking at the indifferent and cold looking Lu Ziji, True Lord Pengyun trembled all over.

Because only the people in Jianbao Pavilion know the specific location of Liu Yan Shenjun s secret realm.What daughter wouldn t be tempted by such a talented and handsome man Wow At this time, Lu Yu suddenly activated the magic formula, and the fire of Nirvana was wrapped around the low grade spiritual weapon level alchemy furnace in front of them.

Who said that the magic Melatonin Gummies for Adults Side Effects: A Comprehensive Guide (dUdhK) weapon belonged to Yan Xunnan Without Yan Xunnan s consent, he would not have CBD Gummy Manufacturing Equipment - Streamline Your Production been able to escape alone from the siege of tens of thousands of mutated poisonous demon bees What s more, he still wants to pursue Yan Xunnan.Otherwise, Shao Zhengqing would not have complained Understanding the Benefits and Uses of Ananda CBD Gummies and swallowed his breath.

It s better Platinum CBD Gummies: Benefits, Effects, and Reviews - CBD Gummy Bears to resist the attack of the ancient demon clan s strong men On Chiyunxing s side, there was only one of the few great powers of Hedao, Ancestor Xiaoyao, who couldn t help but sigh.But he didn t mind it too much, because Yang Rong was the person he promised Zhuang Yu to kill.

There must have been traces of the Suzaku Sacred Bird s presence and its aura The pure blood Suzaku is a true spirit of the fire element, no less than a true dragon or a true phoenix With the fifth grade Vermillion Bird Sacred Tree at its command, the Xihuang Palace is comparable to a fifth grade spiritual place.

In front of Discover How David Harbour’s Intense Workout Routine Led to an Impressive 2 Inches Off His Waistline Lu Yu s powerful punch, it exploded and exploded And Lu Yu s fist hit Lian Bing s head mercilessly, like a The Benefits and Effects of 125 mg CBD Gummies: A Comprehensive Guide (yaSpg) devastating blow Bang In an instant, this true disciple of the Shenghua Sect exploded, completely shattered into powder from beginning to end.I don t know how to solve it Wait for me to rest for a while and then go investigate again However, I don t know how to solve it , According to my guess, as long as you pass the stone bridge normally, you will not be attacked by this water mist Then everyone will follow my footsteps and you will have no worries Hearing Huan Yu s words, everyone suddenly felt relieved.

This Lu Zhen was really slapped in the face, he didn The Benefits of ED CBD Gummies for Erectile Dysfunction: A Comprehensive Guide (laYdD) t expect to be so thick skinned.This is not the evil genius who successively killed Zhao Xuan, Shen Binghong, and Zhao Zhong.

After coming out, Elder Yuan alone is probably no match for Lu Ziji.Even if our Shenghua Sect is a top immortal cultivator, The Nascent Soul stage powerhouse has just broken Side Effects of CBD Gummies 25mg: Benefits, Dosage, and Safety through 100, and now it has lost one tenth Damn it Who did it It can t be Lu Ziji, the Jindan stage casual cultivator, he doesn t have such strength Yes, a mere casual cultivator in the Golden Core stage is like an ant.

Xu Fangyuan s giant palm grabbed a Liu Yan puppet. Others, not to be outdone, grabbed him one after another.Shao Zhengqing then chased the direction Lu Fresh Market signals new growth phase at Oyhut Bay Ziji and others left and fled as fast as possible.

As long as all the Gu insects are not killed, he cannot be killed And every Gu insect is unpredictable and extremely dangerous Before, my second uncle Long Hai was severely injured in front of the Immortal Gu God Jiang Yan, who is from the Shennong lineage, is good at saving people, but he is also good at killing people.

Whoosh At this moment, streaks of light flashed past and landed in front of the Cangshan Sect s gate, revealing figures one after another, wearing the Cangshan Sect s white Hanfu, with high crowns and elegant belts, and extraordinary temperament.It seems that Yan Xunnan must The Benefits and Effectiveness of Vlasic CBD Gummies for Relaxation and Recovery (ByYmG) have been born well and be pampered by his elders, otherwise he would not be so kind and pure at heart.

Many people even think that Fang Siya is a high achiever.As he Experience the Ultimate Life Boost with Life Boost CBD Gummies 300 Mg: Unlock a New Era of Wellness spoke, he warned Lu Yu with cold eyes, as if he was warning the toad not to eat swan meat Lu Finding the Best Sleep Gummies UK for a Restful Night's Sleep (nCNnW) Yu didn t care about the old man s gaze, and said leisurely with a smile on his lips Okay He Yan er s eyebrows suddenly rose, obviously very happy, and then apologized Brother, before going to the secret realm, Yan er does have other things to do.

ah At least they are all immortal cultivators in the late Nascent Soul stage However, without the slightest ability to resist, it was reduced to ashes in the sky burning flames just now Many others were also injured.

What s disappointing is that my thousand year cultivation is not as good as that of a thirty year old junior, Lu Ziji, who is also a good friend of his youngest daughter, He Yan er Happy things, the more miraculous Lu Ziji is, the greater the Understanding the Benefits of Pure Harmony CBD Gummies Reviews: A Comprehensive Guide probability that Lu Ziji can save the Western Wilderness Kingdom As for the members of Finding Relief with the Best CBD Gummies for Tremors: A Comprehensive Guide the Chiyanhu Zhao family, all of them looked gloomy and extremely ugly Especially Zhao Hongzhuang, his face looked like his dead father Shen Binghong s three pronged attack made him think Lu 10 Best Exercises to Lose Weight Fast and Burn More Calories Ziji was dead just now, and he even smiled However, the smile froze in an instant Lu Ziji actually broke this three pronged killing scheme How is it possible After being shocked, Zhao Hongzhuang s eyes looked at Lu Ziji, filled with boundless murderous intent and ferociousness Lu Ziji must die This Vitality Labs CBD Gummies Reviews: How American College Students Achieve Weight Loss Success is not just because of Zhao Guangji s previous blood feud Or because they, the Chiyanhu Zhao family, had offended Lu Ziji so hard The two sides already have a life or death relationship And Lu Ziji, with such a demonic talent, had just broken through the Nascent Soul stage and was able to face off against Shen Binghong, the senior Shen Binghong at the peak of the Divine Stage, without falling behind What if such an existence waits until he breaks through to the Divine Transformation Stage, the Void Refining Stage, or even the Harmony Keto Lean ACV Gummies Reviews: Unlock the Power of Apple Cider Vinegar for Weight Loss and Energy Bo Stage, or the Mahayana Stage Then the Chiyanhu Zhao family will really be wiped out by Lu Ziji At this moment, Zhao Hongzhuang looked at Zhao Zhong, the last of the three people sent by the Zhao family of Red Flame Tiger this time, with a stern Understanding the Benefits and Effects of Anatomyone CBD Gummies look in his eyes He really had no choice but to take care of it But in an instant, Zhao The Best CBD Gummies to Replace Alcohol: A Game-Changing Solution for a Healthier You Hongzhuang s face was filled with joy and laughter, he stroked his beard and laughed and said As expected of my Zhao family s virtuous son in law, Shen Binghong is really great At this moment, within the Qingmu Realm Pearl.

If he cultivates it in the future, it will definitely not be inferior to the Nether Fire Realm Pearl, or even be better At this time, when he saw that in the West Wild Kingdom, in addition to the Cyanwood World Pearl, there was also Harmony Leaf CBD Gummies: A Game-Changing Shark Tank Episode that Will Leave You Harmonious from Hea a cave treasure that was extremely cultivated, such as the Nether Fire World Pearl.

This is the foundation for Bone Sword s future achievements This time, Lu Yu will at least 5 Best Exercises to Lose Weight and Gain Muscle This Winter 2025 recast the bone sword into a high grade spiritual weapon with thirty six Finding the Best Broad Spectrum CBD Gummies for Your Needs Dao patterns, and also lay the foundation for becoming a holy weapon in the future Seeing such a scene, the Scarlet Flame Pavilion weapon spirit was dumbfounded and dumbfounded.

The people of the Cangshan Sect all had pale faces, cold hands and feet, and were trembling as if they had fallen into an ice cellar.What s more Lu Yu narrowed his Full Spectrum CBD Gummies 1500mg: Benefits, Uses, and Reviews eyes slightly. The former lord of the Great Earth Kingdom, Lu Zhen, after taking the follow up technique of the Xuanwu Earth Suppressing Technique, was satisfied and returned to the Great Earth Kingdom.

Now she had to watch Lu Yu and Gou Rui being cruelly poisoned alive by those Can Diabetics Take Keto Gummies for Weight Loss: Separating Fact from Fiction mutated poisonous bees in front of her eyes.From the very beginning, he guessed that the final winner must be Lu Yu Because, in the secret realm of Liu Yan Shenjun s cave, the ancestors in the transformation stage cannot enter.

Master Lu Yu is so amazing Bai Xixi said in a low voice with a slightly red Tami Roman’s Weight Loss Journey: 5 Best Tips for Success Just One Week Before Christmas 2025 face.At this time, they noticed the spatial fluctuations on the Tiantian Road, and their expressions suddenly changed and Cbdynamax for Men Review – Does It Really Support Male Enhancement? they came over.

His strength is even more promising to be an immortal immortal The Benefits and Effectiveness of Sleeping Pills: Melatonin Gummies for a Restful Night's Sleep (nXHdL) and a supreme demon And the other one is just a small Nascent Soul Nature's Truth Sleep Melatonin Gummies: A Comprehensive Guide to Better Sleep (cMHws) stage human race immortal cultivator No matter what the means, no matter how powerful the body training technique is, it is still a world of difference However, Lu Yu was standing in front of him alive.

People s future cultivation will be smoother And the biggest role is to make up for the Dao foundation, which can help the immortal cultivator to reshape the golden elixir If you are an evildoer and take the Xuanhuang Fruit of Heaven and Earth, you may be able to directly create a holy product.He immediately became anxious and quickly stopped him and said anxiously The people who compete in martial arts and discuss martial arts in the Baijiang Conference are all Every one of the talented disciples of the major immortal cultivating sects and major forces is a cultivator above the Golden Core stage, and the magical powers and magic weapons they master are extremely extraordinary, which cannot be compared with ordinary Golden Unlocking Weight Loss Success: Let’s Keto Apple Gummies in Action Core stage Every one of them is a cultivator above the Golden Core stage.

He was not a tough guy to begin with, but he was a little greedy for life and afraid of death, otherwise he would not have run away before and fled in despair.He was from the same line. He was so thick skinned.

However, from the indifferent eyes of this man, and the aura that seems to be playful but does not take everyone seriously, it is very much like the first person in the world who came out of nowhere to conquer the Emperor Star, Lu Ziji, Lu Xianzun But how is that possible That s Cangshan Star And on the other side. Ma Ruihai, the head of the Ma family in Changbai Mountain and Ma Shen s father, saw Lu Yu and Fang Siya being so intimate, and his anger suddenly became more intense.

Lu Yu won a great victory. Wan Zhi, the CBD Gummies for Diabetic: A Game-Changing Solution for Blood Sugar Management leader of Wanli Sect, and other ten god incarnation stage gods fell.Her cultivation was not advanced, and she was separated from the old man Grandpa Yun who was always protecting her.

Soon, Lu Yu took the eleventh step, the twelfth step, the thirteenth step Under the shocked and disbelieving eyes of everyone, Lu Yu walked through this place easily and leisurely.It was Zhou Tianchou s soul Within the core of the soul, there is also a guardian talisman, but it was given by the Yuan Ying stage elder of Fenglei Sect.

He was the most powerful in the world. Now, he was so underestimated by Experience the Revolutionary Power of Keto Rush ACV Gummies: A Comprehensive Guide to Weight Loss an Lu Ziji, a mere junior.It is an unexpected surprise He rushed over and laughed wildly. They didn t notice at all that Lu Yu and the evil ancestor were not afraid at all.

Lu Yu s authority at this time was already the greatest, equivalent to the level of Feng Yao, the Biohealth CBD Gummies Reviews: A Comprehensive Analysis of Cannabidiol Benefits leader of the Cangshan Sect, and all the scriptures and scriptures in the Tibetan Scripture Pavilion were open to him.Donald, President of the Citizen Country, congratulates Mr.

Lu Yu was speechless. The Red Flame Pavilion weapon spirit is too cheating How can you forget such a fatal thing In other words, still hiding it from him It seems that I must make a quick decision Lu Yu frowned.The Ancestor of the Transformation God personally took action Those guys at the Nascent Soul stage and the Golden Core stage are still delusional in trying to shake the formation in the depths Lu Yu has already seen that the secret realm of Liu Yan God Lord s cave is absolutely incredible.

Furthermore, according to my judgment, you are not like an old monster who has been reborn.With such a decisive and indifferent character, it is impossible to persuade him to apologize to the Cangshan Star cultivator.

He immediately cupped his hands and saluted Lu Yu. Lu Yu looked at Li Yi coldly.Although Elder Songjiang and others also hope to go to the upper level of Red Flame Pavilion to get more benefits, since Lian Peng has an order, they dare not disobey it.

You haven t found it for so long. You should be enlightened The space in the misty forest should have been blocked by the ancient demons long ago.

Ye Hui said Besides, the stories this guy tells are quite interesting.However, the biggest surprise is the power of the soul With the power of the soul, Su Ye s cultivation of the spiritual sea has become much simpler.

I don t want it. Human beings cannot be trusted. My master is not an ordinary human being. No matter how unusual he is, he is still a human being.But at this moment On the broken ground, a huge rock turned up. Finding Relief with CBD Gummies for IBS: A Comprehensive Guide (cnuyp) Su Ye s eyes lit up, and he immediately ran towards the rock, and jumped into the air with the help of the upturned rock.

The The Pros and Cons of Losing Weight While Breastfeeding days are long, Mr. Su will understand the meaning of this.The leaves were full and fragrant, and it grew very well.

How much respect can a group of aliens have for the academy Come on, I ll take you.This is called Feng Xiao Jade. If it is a spiritual beast that can control Feng Liu, this jade can increase the PureKana Premium CBD Gummies Reviews: Exploring Their Efficacy in Smoking Cessation for American Adults power of Feng Liu both offensively and defensively.

Su Ye pointed to his head It s the brain. Lu Feiyu looked confused.Under the dim moonlight, a disheveled man was crawling on the ground, his body covered with festering carrion.

Come when you want, leave when you want, do you think I am a bus I really have to get involved and see what treasures there are in this so called secret place.The alchemist who refined this Juxing Powder definitely used a large amount of precious elixirs, making the effects of the medicine quite terrifying.

After about a cup of tea, Su Ye s whole body looked as if it had been boiled in water.The same is true for Su Ye. He is currently wearing a lined singlet.

What do you want to do, you Gummies for Pain and Sleep: A Comprehensive Guide to Relief (HSAQG) guy The national treasure looked at Su Ye pitifully.Fortunately, Yunyicheng is not far from Montenegro.

Diplodocus turned his head fiercely Boy from the Su family, what do you think we should do Ah I said Canodyne CBD Gel Reviews: A Comprehensive Guide to Effective Pain Relief for Sports Injuries (eFvVo) Su Ye looked at the cup I think Comprehensive CBD Vape Oil Review: A Detailed Analysis of Quality and Effectiveness (xQcmG) You can make a drink yourself.Ghost Su Ye was not surprised. Demons and demons all have human forms, but when necessary, they can also transform into four fighting forms demon, charm, demon, and demon.

The two flying yakshas widened their eyes and looked back sharply, and then they saw a figure emerging from the sand.Now it can reach his waist, and his tonnage is getting heavier and heavier.

I m back. Yu Ziya continued to apply medicine as if meeting an old friend he hadn t seen for a long time, and said, How was it After five years of being a savage in the mountains, have you gained anything Not bad, my cultivation has improved a bit.Shopkeeper Rong is an expert in doing business. Su Ye said with a smile Use Liang Guogong to burn the fire a little more.

After returning to his hut, Su Ye lamented and then entered the world of Hell The world of the Prison of the Undead, the Feitian Yaksha Walled City.In this case, you should know my sincerity. However, swordsmanship and magical powers cannot be bought with spiritual crystals.

You can only lose money. This is why Su Ye took out the four magical artifacts and sold them directly.You can choose the specific types by yourself, including common spiritual materials and elixirs on the market.

If you haven t found the elixir yet, then you are somewhat mentally retarded.Don t tell me, that old boy Diplodocus knows how to enjoy it, and even prepared a variety of condiments.

The Rakshasa girl hurriedly swung her whip and hit the fireball, and then the fireball exploded instantly.In addition, as it is an annual grand event in Yanjing City, there will naturally be a lot of people joining in the fun, but they will stay away from the students in the academy and let the students go up the mountain The Benefits and Uses of Wellness Farms CBD Gummies 750mg for Holistic Health (nEtOf) first.

Stop running around. Luo Qingqing lowered her voice and said, What if something happens Don t worry, these people are waiting.In a world like the Wilderness World where cultivation resources are relatively scarce, they are not considered rare and are not eye catching when taken out.

Su Ye said First, as I just said, there is no need to use Soul Condensing Pill in this situation.The Drowned Ghost thought for a while and said There is a camp outside Ice Knife Mountain.

But I m afraid I don t have the intention of abolishing the elders and establishing the younger ones, so some people may not be able to sit still.It was always a good thing to have a guide. Okay Su Ye agreed, Let s go to the underground palace to play.

He is very powerful. He is a powerful man in the Nascent Soul stage.Because something is wrong It should be daytime Finding the Best Gummies for Sleep Nearby: A Comprehensive Guide to Restful Nights (nAooA) now However, when Su Ye walked out of the house, he found that there was no one around, the sky was dark, and a full moon hung high in the sky.

If they are used to refine weapons, the quality will most likely be superior to spiritual weapons.