LTCPAA

Long Term Measurements of Chemical and Physical Properties of Atmospheric Aerosol at Dome C

LTCPAA

© PNRA

Progetto

Questo progetto prevede l’installazione di un laboratorio che permetta di effettuare misure a lungo termine delle proprietà chimiche e fisiche dell’aerosol atmosferico a Dome C. Questo tipo di misure è fondamentale per comprendere meglio le sorgenti attuali del particolato e dei gas atmosferici, i loro processi di trasporto a lungo raggio, i loro meccanismi deposizionali e post-deposizionali, e la loro trasformazione chimica. L’ottenimento di un data set sufficientemente ampio è basilare sia per la comprensione delle variabili che influenzano il clima odierno, sia per una corretta interpretazione dei record paleoambientali da carote di ghiaccio, oltre che per la calibrazione dei modelli previsionali.

Oltre allo studio delle proprietà fisiche e chimiche dell’aerosol e dei gas atmosferici come l’ozono, è anche continuamente misurato il flusso di raggi cosmici per lo studio dell’attività solare e della precipitazione delle particelle ad alta energia.

Project

This project has main target the installation of a laboratory that allows to carry out long-term measurements of the chemical and physical properties of atmospheric aerosol at Dome C. This kind of measurement is fundamental to better understand the current sources of particulate matter and atmospheric gases, their long-range transport processes, their depositional and post-depositional mechanisms, and their chemical transformation. The achievement of a sufficiently large data set is fundamental both for understanding the variables that influence today's climate and for a correct interpretation of paleo-environmental records from ice cores, as well as for the calibration of predictive models.

Besides the study of the chemical and physical properties of atmospheric aerosol and gaseous as ozone, it is also measured continuously the cosmic ray flux for the study of the solar activity and the precipitation of high energy particles.

Scientific Objectives

  • understanding the climate-aerosol feedback processes in regions that are very sensitive to environmental and climatic changes;
  • establishing the background values of the atmospheric load, size distribution and chemical composition of aerosol;
  • improving the reliability of climatic models by making available a long-term data set for a more effective evaluation of the forcings exerted by global aerosol (ERFari and ERFaci);
  • studying, with sufficient statistics, the seasonal and inter-annual trend of the concentrations of key-components of aerosol (S-, N- and C-cycle compounds; biogenic emissions; dust; sea spray);
  • evaluating the present source strength and long-range atmospheric transport efficiency of aerosol produced in the marine and continental areas at lower latitudes;
  • estimating the contribution of aerosol sources to Antarctica from local to regional scale;
  • studying the effects of photochemistry and radical sources (ozone) on chemical reactions of gaseous aerosol precursors and New Particles Formation in very peculiar (temperature, continuous summer irradiance) atmospheric conditions;
  • improving the reliability of paleo-climatic and paleo-environmental reconstructions by ice core stratigraphies, also by a better knowledge of the aerosol- snow surface interchange;
  • evaluating the possible role of cosmic rays in New Particle Formation (NPF) in an area where nucleation is unlikely due to low atmospheric concentrations of aerosol precursors.

Research Activities

Dome C

Dome C site (75°06′S, 123°21′E) is located at 3233 m a.s.l. on the East Antarctic plateau south of the Indian Ocean, about 1100 km from the coastline. Located on the top of a large dome with negligible slope, Dome C is not affected by the typical intense katabatic winds observed in Antarctica. The thickness of the ice cap is 3250±25 m, has a mean annual temperature of −53°C and a mean annual accumulation rate of some tens of mm of equivalent water (corresponding to about 7.4 cm of snow) per year at the surface. This small accumulation rate is due to the very low humidity in the atmosphere.

Dome C represents a strategic place for these studies, thanks to the remote location of the site, which is characterized by very low levels of contamination (both for the distance of the major sources of particulate and the high altitude, besides the isolation due to the establish of the winter polar vortex) and the proximity to the minimum of the geomagnetic field, which allow to measure a cosmic ray flux relatively high.

Shelters

Surface snow (roughly 1 cm depth) is collected in a dedicated area, called "CLEAN AREA", 200 m far from ATMOS shelter
The ATMOS shelter is located at about 700 m away from Concordia Base, in an upwind position with respect to the prevailing winds, in order to minimize contamination from Base’s emissions. The shelter is devoted to all the chemical and glaciological experiments
The PHYSIC shelter is located at about 600 m away from Concordia Station. The shelter is devoted to all the physical experiments

Instruments

Daily automatic low-volume PM10 aerosol
4-stage inertial impactor size-segregated aerosol
Bulk low-volume PM10 aerosol
Bulk medium-volume PM10 aerosol
Bulk high-volume PM10 aerosol
Ozone analyzer
DMPS (Differential Mobility Particle Sizer)
Nephelometer
PSAP (Particle Soot Absorption Photometer)
OPS (Optical Particle Sizer)
CIC (Cluster ion counter)
Muon Counter (AMiCO)
Neutron Counter

About Us

Principal Investigator:
Prof. Rita Traversi - rita.traversi@unifi.it

Unit Responsible: Prof. Rita Traversi (University of Florence – traversi@unifi.it)

University of Florence (Silvia Becagli, Mirko Severi, Laura Caiazzo – currently INFN Florence, Alessandra Amore, Raffaello Nardin, Rita Traversi)

  • Set up of an array of sampling and measurement devices to be used for long-term studies (bulk PM10 at low and medium vol., 4-stage impactors)
  • Devoted chemical analyses (ion content, major and trace metals, EC/OC) on continuously collected aerosol and snow samples

 

INFN Florence (National Institute of Nuclear Physics) and Department of Physics and Astronomy, University of Florence (Lorenzo Bonechi, Raffaello d’Alessandro)

  • Continuous measurement of Cosmic Ray flux by Muon Counter (AMiCO) to study possible correlations with the rate of production of particulate matter and atmospheric conditions

 

University of Oulu – Finland (FINNARP and Academy of Finland Project: CRIPA – “Cosmic Rays In Polar Atmosphere” – PI: Prof. Ilya Usoskin, Stepan Poluianov)

  • Continuous measurement of Cosmic Ray flux variability in the high-elevation polar atmosphere and study of their effects by 2 Neutron Monitors

Unit Responsible: Dr. Paolo Cristofanelli (CNR-ISAC Bologna– paolo.cristofanelli@isac.cnr.it)

CNR-ISAC Bologna (Paolo Cristofanelli, Davide Putero, Francesco Calzolari, Maurizio Busetto)

  • Investigation of the variability of near-surface ozone and aerosol physical properties (absorption and scattering coefficient, size distribution) in the continental Antarctic PBL
  • Related performing of QA/QC actions to assure the quality of recorded data

 

CNR-IIA, Rome (A. Ianniello, F. Vichi, G. Esposito, M. Frattoni, A. Imperiali)

  • Summer campaigns of sampling and analysis of VOCs and gas/particulate repartition for N-cycle species

 

FMI (Finnish Meteorological Institute) and UHEL (University of Helsinki) – Finland (Aki Virkkula, John Backman, Pasi Aalto)

  • Continuous measurements of size distribution, light scattering and absorption measurements, cluster ion counting

Unit Responsible: Prof. Andrea Gambaro (University of Ca’ Foscari, Venice – gambaro@unive.it)

University of Ca’ Foscari, Venice (Andrea Gambaro, Elena Barbaro, Matteo Feltracco)

  • Summer campaigns of PM10 aerosol sampling and analysis of a number of species: 40 free L- and D- amino acids, 7 monosaccharides (arabinose, fructose, galactose, glucose, mannose, ribose, xylose), 8 alcohol-sugars (arabitol, erythritol, mannitol, ribitol, sorbitol, xylitol, galactitol, maltitol), 3 anhydrosugars (levoglucosan, mannosan and galactosan), sucrose, 11 phenolic compounds (PC) (vanillic acid, isovanillic acid, homovanillic acid, vanillin, syringic acid, syringaldehyde, p-coumaric acid, coniferaldehyde, acetosyringone, acetovanillone and ferrulic acid)

Unit Responsible: Prof. Marco Grotti (University of Genova – grotti@unige.it)

University of Genova (Marco Grotti, Francisco Ardini)

  • Elemental and isotopic analysis of PM10 aerosol and snow samples (in collaboration with SIDDARTA project)

Metadata

Kind of Sampling Location From (date) To (date) Resolution Time Type of Measurement Research Unit (RU)
Skypost PM10 ATMOS shelter 05/12/2016 Currently ongoing Daily Bulk PM10 by low-volume sampler devoted to the analysis of chemical ionic markers RU 1 - University of Florence
Dekati-4 ATMOS shelter 05/12/2016 Currently ongoing 4 days Size-segregated aerosol by 4-stage inertial impactor by low-volume sampler devoted to the analysis of ionic markers and major metals RU 1 - University of Florence
PM10 ECHO-PM ATMOS shelter 13/12/2016 Currently ongoing 8 days Bulk PM10 by low-volume sampler devoted to the measurements of Elemental and Organic Carbon RU 1 - University of Florence
PM10 ECHO-PUF ATMOS shelter 28/01/2017 Currently ongoing 32 days Bulk PM10 by medium-volume sampler devoted to the determination of main and trace metals by ICP-MS and PIXE techniques RU 1 - University of Florence / RU 4 - University of Genova
Surface Snow Clean Area 05/12/2016 Currently ongoing 2 days Measurements devoted to the analysis of chemical ionic markers RU 1 - University of Florence
Muon Counter (AMiCO) PHYSIC shelter 23/12/2017 Currently ongoing 1 minute Continuous monitoring of the charged cosmic rays intensity RU 1 - INFN of Florence
Neutron Counter PHYSIC shelter December 2014 Currently ongoing 1 minute Cosmic Ray Flux measurements RU 1 - University of Oulu
Ozone analyzer ATMOS shelter December 2016 Currently ongoing 1 minute Measurements of variability of near-surface ozone RU 2 - CNR-ISAC of Bologna
DMPS ATMOS shelter December 2007 Currently ongoing 13 minutes Differential Mobility Particle Sizer: measurements of particle size distribution in the 10 - 1000 nm size range RU 2 - FMI and UHEL of Helsinki
OPS ATMOS shelter December 2007 Currently ongoing 10 minutes Optical Particle Sizer: measurements of particle size distribution in the 0.3 - 10 nm RU 2 - FMI and UHEL of Helsinki
Nephelometer ATMOS shelter December 2007 Currently ongoing 3 seconds Measurements of scattering e backscattering radiation at 3 wavelengths RU 2 - FMI and UHEL of Helsinki
PSAP ATMOS shelter December 2007 Currently ongoing 1 second Particle Soot Absorption Photometer: Measurements of absorption at 3 wavelengths (660, 530, 467 nm) RU 2 - FMI and UHEL of Helsinki
CIC ATMOS shelter December 2018 Currently ongoing 1 second Cluster ion counter: measurements of ion size distributions in the sub 1 nm to about 3 nm RU 2 - FMI and UHEL of Helsinki
HV-PM10 Roof of ATMOS shelter 2016-2017, 2017-2018, 2018-2019, 2019-2020 summer campaigns Currently ongoing during summer 10 days Multi-stage high volume impactor devoted to the analysis of phenolic compounds, free amino acids and sugars RU 3 - University Ca' Foscari of Venice
Surface Snow Clean Area December 2016 Currently ongoing 30 days Measurements devoted to the analysis of isotopic analysis by ICP-AES, ICP-QMS or ICP-SF-MS RU 4 - University of Genova

Summer Campaigns

2016/2017 Summer Campaing:

  • Equipping a new laboratory in the "ATMOS" shelter with several sampling and measurement devices:
    • 1 Skypost for daily PM10 sampling
    • 1 ECHO-PM for the 4-stage impactor Dekati-4, with 4-day resolution
    • 2 ECHO-PUF for the metal sampling, with 32-day resolution
    • 1 ECHO-PM for EC-OC, elementary and organic carbon, sampling, with 8-day resolution
    • 1 ECHO-PM for the daily NO3- sampling, lasted only 4 months in total, during the summer campaign and the first period of the winter campaign
    • 1 high-volume sampler for halogen sampling, during the summer campaign
    • ozone analyser
    • a meteorological trigger with an anemometer on the roof, to prevent possible influences of the Base
  • Holing the wooden plates on the roof of the shelter, insulating them with the rockwool panels, and allowing the passage of the metal pipes and temperature probes connecting samplers (inside the shelter) to the cut-off heads (on the roof)
  • Putting on wooden panels the aspiration pumps, in order to dampen vibrations and related noise
  • Building specific housings (by wood and polyethylene plates) to prevent snow accumulation on the sampling head on the roof
  • Carrying out maintenance and instrument intercomparisons of continuous size distribution measurements:
    • nephelometer
    • DMPS
    • OPS
    • PSAP
  • Starting with superficial snow samples collected in the “clean area”

2017/2018 Summer Campaing:

  • Prosecution of the atmospheric and superficial snow sampling
  • Halogen sampling with a high-volume sampler during the summer campaign
  • Atmospheric measurements of the largest portion of the organic fraction (VOC, aldehydes, carboxylic acids) during summer period
  • Installing of a new anemometer and trigger
  • Installing of the muon counter
  • Intercomparison of PSAP system with a similar system calibrated
  • Checking of DMPS performances by intercomparison with a portable CPC (Condensation Particle Counter)
  • Packing of all the samples at -20°C ready for shipping to Italy
  • Training to the new winterover personnel

2018/2019 Summer Campaign:

  • Prosecution of the atmospheric and superficial snow sampling
  • Annual checking and maintenance of all the instrumental set: atmospheric aerosol samplers, aspiration pumps, particle counters and ozone analyser
  • Atmospheric measurements of the largest portion of the organic fraction (VOC, aldehydes, carboxylic acids) during summer period
  • Substitution of all the cables of the high-volume sampler and starting of the halogen sampling during summer period
  • Back-up of all the data registered during the previous winter period
  • Rearrangement of the anemometer on the roof of the shelter and changing the set-up of the trigger program for stopping the pumps
  • Reorganization of the rooms inside ATMOS shelter
  • Removal of the wooden housing on the roof
  • Replacing of the PSAP instrument with a less noisy one
  • Installation of the Cluster Ion Counter (CIC)
  • Packing of all the samples at -20°C ready for shipping to Italy
  • Training to the new winterover personnel

2019/2020 Summer Campaign:

  • Prosecution of the atmospheric and superficial snow sampling
  • Annual checking and maintenance of all the instrumental set: atmospheric aerosol samplers, aspiration pumps, particle counters, ozone analyser, and neutron and muon counters
  • Halogen sampling with a high-volume sampler during the summer campaign
  • Back-up of all the data registered during the previous winter period
  • Substitution of the connection cable of the anemometer and of the relays of the meteorological trigger
  • Adding of some function in the trigger’s program
  • Packing and sending back to Italy the Skypost and substitution with a new automatic PM10 sampler (Giano DadoLab)
  • Packing of all the samples at -20°C ready for shipping to Italy
  • Training to the new winterover personnel

Collaborations

INTERNATIONAL COLLABORATIONS AND SCIENTISTS INVOLVED

  • IGE (Grenoble, France). Dr. J. Savarino – N-species sources and air/snow processes; Dr. M. Legrand – biogenic S compounds; Dr. B. Jourdain – sea spray aerosol
  • KOPRI (Incheon, South Korea). Dr. Y.J. Yoon. Comparison of aerosol chemical and physical properties with other Antarctic sites, King Sejong Station and Jang Bogo Station
  • Institute of Alpine and Arctic Research (INSTAAR); University of Colorado (Boulder, USA). Dr. D. Helmig: N-cycle compounds at DC and comparison South Pole – DC aerosol
  • Desert Research Institute (Reno, Nevada). Prof. J. McConnell: comparison South Pole – DC aerosol and ice core stratigraphies study
  • University of Ghent (Ghent, Belgium). Prof. F. Vanhaecke. Pb, Sr and Nd isotopic ratio by multi-collector ICP-MS measurements
  • Sodankylä Geophys. Obs. (Sodankylä, Finland), University of Oulu. Prof. I.G. Usoskin, Dr. S. Poluianov: Cosmic Rays monitoring
  • FMI (Helsinki, Finland). Dr. A. Virkkula. Continuous size distribution measurements by OPC and DMPS
  • Joint Antarctic Research Institute (Wellington, NZ). Prof. N. Bertler: geochemical cycles, mineral dust source areas and ice core records.
  • EMPA (CH). Dr. C. Zelwegger: World calibration Center Surface O3

COLLABORATIONS ON FIELD

  • Personnel of SIDDARTA project (P.I. Silvia Nava)
  • Personnel of BrHgSnow project (P.I. Andrea Spolaor)
  • Personnel of BSRN project (P.I. Angelo Lupi)

Publications

Poluianov, S.V., I.G. Usoskin, A.L. Mishev, et al., GLE and Sub-GLE Redefinition in the Light of High- Altitude Polar Neutron Monitors, Solar Phys., 292, 176, 2017, doi: 10.1007/s11207-017-1202-4.

Poluianov, S., I. Usoskin, A. Mishev, et al. Revisited definition of GLE, Proc. Sci. (ICRC2017), Proc. 35rd Internat. Cosmic Ray Conf., Busan, 125, 2017.

Cristofanelli et al., Analysis of multi-year near-surface ozone observations at the WMO/GAW “Concordia” station (75°06′S, 123°20′E, 3280 m a.s.l. – Antarctica), Atmospheric Environment, 177, 54-63, 2018.

Mishev, A.L., I.G. Usoskin, Assessment of the radiation environment at commercial jet-flight altitudes during GLE 72 on 10 September 2017 using neutron monitor data, Space Weather, 16, 1921-1929, 2018, doi: 10.1029/2018SW001946.

Gil, A., G.A. Kovaltsov, V.V. Mikhailov, A. Mishev, S. Poluianov and I.G. Usoskin, An Anisotropic Cosmic-Ray Enhancement Event on 07-June-2015: A Possible Origin, Solar Phys., 293, 154, 2018, doi: 10.1007/s11207-018-1375-5.

Mishev, A., I. Usoskin, O. Raukunen, M. Paassilta, E. Valtonen, L. Kocharov, R. Vainio, First Analysis of Ground-Level Enhancement (GLE) 72 on 10 September 2017: Spectral and Anisotropy Characteristics, Solar Phys., 293, 136, 2018, doi: 10.1007/s11207-018-1354-x.

Mishev, A., I. Usoskin, Analysis of sub-GLE and GLE events using NM data: space weather applications, J. of Phys.: Conf. Series, 1, 1181, 2019, doi: 10.1088/1742-6596/1181/1/012006.

Conference Contributions

Traversi, R., S. Becagli, L. Caiazzo, M. Busetto, F. Calzolari, P. Cristofanelli, B. Petkov, M. Severi. Composizione chimica dell’aerosol atmosferico e della neve superficiale a Dome C (Antartide Orientale) risultati da 10 anni di attività. ORAL. “VIII Convegno Nazionale sul Particolato Atmosferico” PM2018 – 23-25 Maggio 2018, Matera.

Becagli, S., R. Traversi, M. Severi, L. Caiazzo, L. Lazzara, G. Mori, C. Marchese, C. Scarchilli, V. Ciardini. Aerosol biogenico in Antartide centrale. Deduzioni sulle interazioni oceano-atmosfera. ORAL. “VIII Convegno Nazionale sul Particolato Atmosferico” PM2018 – 23-25 Maggio 2018, Matera.

Traversi, R., S. Becagli, L. Caiazzo, M. Busetto, F. Calzolari, P. Cristofanelli, B. Petkov, M. Severi. Aerosol and Surface Snow Chemical Composition at Dome C from 10-yr Long Records. ORAL. “A SCAR & IASC Conference” Polar2018 – 15-26 June 2018, Davos.

Becagli, S., R. Traversi, M. Severi, L. Caiazzo, L. Lazzara, G. Mori, C. Marchese, C. Scarchilli, V. Ciardini. Biogenic Aerosol in Central Antarctica: The Ocean-atmosphere Interaction. POSTER. “A SCAR & IASC Conference” Polar2018 – 15-26 June 2018, Davos.

Virkkula, A., V.-M. Kerminen, T.Petäjä, G. De Leeuw, E. Asmi, D. Brus, T. Laurila, H. Timonen, K. Teinilä, E. Rodriquez, J. Svensson, V. Aaltonen, J. Backman, R. Hillamo, M. Sipilä, T. Jokinen, E. Järvinen, T. Nieminen, R. Väänänen, H. Manninen, X. Chen, P.P. Aalto, H. Grythe, M. Busetto, C. Lanconelli, A. Lupi, V. Vitale, R. Weller, A.C. Saulo, and M. Kulmala: Final results of a project on Antarctic aerosols in 2013 -2016. Proceedings of the NOSA-FAAR Symposium 2018, Report Series in Aerosol Science, 208, 134 (http://www.atm.helsinki.fi/FAAR/reportseries/rs-208.pdf), 2018.

Virkkula, A., Grythe, H., Backman, J., Aalto, P.P, Petäjä, T., Busetto, M., Lupi, A., Vitale, V., Udisti, R., Becagli, S., Sheridan, P., Ogren, J., and Kulmala, M.: Surface Aerosols at Dome C and Comparison with Observations at the South Pole, Abstract nr. 2499. “A SCAR & IASC Conference” Polar2018 – 15-26 June 2018, Davos.

Traversi, R., S. Becagli, L. Caiazzo, M. Busetto, F. Calzolari, P. Cristofanelli, B. Petkov, M. Severi. KEYNOTE. Chemical composition of atmospheric aerosol and surface snow at Dome C (East Antarctic Ice Sheet): an overview from 10-yr long records. “XXVII Congresso della Divisione di Chimica Analitica” – 16-20 Settembre 2018, Bologna, Italy.

Becagli, S., R. Traversi, M. Severi, L. Caiazzo, L. Lazzara, C. Marchese. Insight on the Ocean- Atmosphere interaction in polar Southern Emisphere by long term aerosol measurements in Central Antarctica. POSTER. “XXVII Congresso della Divisione di Chimica Analitica” – 16-20 Settembre 2018, Bologna, Italy.

Lascia un commento

Agenzia nazionale per le nuove tecnologie,
l'energia e lo sviluppo economico sostenibile
Unità Tecnica Antartide

Jiang Yuebai used all his strength to lift a dead tree stump that was bigger than the puddle and threw it towards Water Lily.A strange and vibrant world unfolded before Jiang Yuebai CBD Gummy Bears 300mg: A Comprehensive Guide to Their Benefits and Uses (szSWF) s eyes, filling her with curiosity and exploration.

For thirteen years, I devoted myself to the Yun State and helped the women of the Yun State to gain more opportunities to enter the officialdom.This time, it was as violent as a volcanic eruption.

The heavy rain was icy and bone chilling, all containing Xuan Yin evil spirits.After returning to the clan, Zhao Xiu lost his mind and locked himself in the Tiangang Peak Hall.

There is also the Secret Code of the Fire Refined Sky written by True Lord Canghuo, Wrapping Feet in Apple Cider Vinegar to Lose Weight: 3 Fitness Coaches’ Success Stories in 2025 which contains a body building part, and is The Benefits of Gummy Bears for Diabetes: A Comprehensive Guide (ypuIr) the best technique for him.It is absolutely impossible to call them Xiuwei. Maybe even their names are fake.

Jiang Finding Restful Sleep with CBD Sleep Gummies without Melatonin: A Comprehensive Guide (cyRmA) Yuebai had a hunch that this was probably the source of the Spruce CBD Review: A Comprehensive Analysis of the Brand's Products and Benefits (TsSTf) Five Elements.The young man Chu He looked seriously, nodded and Clinical Insights: Ariana Grande Weight Loss Photos – Evidence-Based Analysis of the Change said, Fifth senior brother, don t worry, I will definitely work hard.

Greetings to Master Wangshu. Jiang Yuebai looked over one by one from left to right.In a blink of an eye, they found that the surroundings had turned into a vast expanse of yellow sand, with flying swords hanging above their heads, showing murderous intent.

The rear was in Best Appetite Suppressants for Hunger Control and Weight Loss in 2025 chaos, and the front line was also affected.Now that I have this ability, I have to fight, even if it can only play a small role.

Hong Tao squeezed the storage bag a little nervously, originally he had agreed to only pledge a hundred lower grade spiritual stones.Wake up Jiang Yuebai s The Importance of Effective CBD Gummy Packaging: Enhancing Your Product's Appeal and Safety scalp felt numb and his pupils shrank sharply.

Partly, it also helps with kendo. For Harmony Leaf CBD Gummies Dr Oz - Natural Relief for Anxiety, Pain & Stress example, the method of forging the body in the Barbarian Divine Art , the method of controlling the sword energy in the Golden Snake Sword Palm , and the method of lifting The Rick Ross Weight Loss Phenomenon: How His Journey Inspires Others to Pursue a Healthier Lifestyle light as if it were Finding the Highest Potency CBD Gummies for Enhanced Relaxation and Sleep (PPLsy) heavy in Six Yang Hammer Technique can also be integrated into the way of swordsmanship.

He had an air of immortality, his brows were indifferent, and he had an awe inspiring aura.Incense money is rarer than spiritual stones and magic stones.

Jiang Yuebai thought about it, and his consciousness seemed to be stretched infinitely, looking down from the sky.The Iron Feather National Defense is well defended, and even the spies from Hongyan Tower can t sneak in.

It was just covered with dead leaves and a few snow white pictures hung on it.He suddenly felt like these ants. Even if he became the strongest one in the ant colony, he could still be easily trampled to death by people.

I know that they are willing to do it for you, the Dragon King, and they also need your leadership, but your current leadership is Where Can I Buy Bioheal CBD Gummies: A Comprehensive Guide (Ffsar) pushing them into the abyss of eternal destruction.After so many years, Jiang Yuebai formed the elixir, and he only reached the peak of his foundation building.

Seeing Jiang Yuebai s Qichengyue, the female phoenix and the male phoenix looked surprised.If you don t come, , I lifted up your Wen family s mountain defense formation As soon as he finished speaking, Zhao Fuyi didn t wait for Wen Hong to speak, Does Walgreens Sell CBD Gummies: A Comprehensive Guide and drove a ray of light straight towards the East China Sea.

If you encounter difficulties in the future, you must stop and think first.The white wolf just now Wang She glanced at it from a distance and saw that she had the strength of the middle 10 Nutrient-Packed Low-Fat Recipes That Help You Lose Weight in Los Angeles How Seth Rogen’s Weight Loss Journey Inspires and Teaches Us and late stages of Jin Dan.

Her poems shocked the world. The blue sky and white sun were shining brightly.The breath of dragon essence and blood. This aura cannot be detected by monks, but it is an aura that Understanding the Benefits of Vena CBD Gummies for Restful Sleep and Relaxation cannot be ignored by dragons.

On the fire cauldron, sixty four small pieces of meteorite iron were suspended in the air.One Experience the Power of Oprah Winfrey's Keto Gummy Bears: A Game-Changing Snack for a Healthier You faces upwards to the north and the other faces downwards Comprehensive Analysis of Pure CBD Now Reviews: A Deep Dive into the World of CBD Products (SPbqy) to the west.

Try to reconcile the five elements with this, and melt the spiritual energy of the five Cannabis Gummies Benefits: A Comprehensive Guide to Edible Gummies (vtLbC) elements into the Dantian cyclone Can Dogs Eat CBD Gummies: A Comprehensive Guide (KIslj) to condense it into a Qi Dan.Now I am the swordsman genius who will form the elixir and forge the supreme sword bone Comprehensive Review of Muscle MX CBD Balm: Analyzing User Feedback and Expert Opinions (VMtzo) at the age of thirty three, Xie Clan Jingshan Luo Tingzong laughed and shook his head, If you had awakened earlier and accepted the help of the ancestor earlier, I am afraid you would have broken the record of the 32 year old Guiyuan Sword Sect s pill formation, which Best Ways Kelly Clarkson Lost Her Weight to Inspire You Two Weeks Before Christmas was the fastest pill formation record in the Revolutionize Your Weight Loss Journey: Keto Gummies Endorsed by Shark Tank - Do They Really Work fo entire earth spirit world.

They wanted to trap the Yinglong, but What is CBD Gummies Meaning: Understanding Benefits and Uses it was already almost two years ago.Jiang Yuebai stood up and patted Xie Jingshan s head, Don t worry, Brother Dog, I won t let you spend ten thousand high grade spiritual stones in vain.

A phoenix cry came from high in the sky, and the Qingqiu Fox Clan stopped one after another, looking up to see two little phoenixes flying down from the crown of the sacred tree one after another, spreading Green Lobster CBD Gummies Amazon - Reviews, Benefits, and Uses their wings and soaring majestically.Let s go, the top of the tree should not be far away.

The sword calamus on the grass dragon Fast Track to Weight Loss: Proven Methods for Rapid and Lasting Results tried to spread out again, but as soon as it was extended, an electric current was set off on the golden talisman chain.With a wave Biolyfe Keto Gummies Side Effects: A Comprehensive Review of the Benefits and Risks of Using Keto Gu of its claws, a large piece of sword calamus Can Diabetics Take Apple Cider Gummies: A Comprehensive Guide (XCmrz) was flattened, and the flying grass blades were sucked away by a strange force and disappeared.

To enter Tian Crying Peak as a direct disciple, there are three conditions.Boom Deep in Leize, the sound of thunder suddenly intensified, and the Achieve Your Fitness Goals: Weight Loss Tips Without Gym strong wind rolled up the black The Truth About Power CBD Gummies Shark Tank: Separating Fact from Fiction (NTQEW) sand, covering the sky and the sun.

Threads are more edible than before. In my previous confusion, I almost ate Jixiang because she was eating inside.To reach the top of the tree, qualifications, perseverance, strength Revolutionize Your Keto Journey with Costco ACV Keto Gummies: A Game-Changing Weight Loss Supplement and wisdom are all indispensable.

Deep in the dry forest, a huge tomb exploded, leaving Kanna CBD Gummies Review: Benefits, Ingredients & User Insights a shocking pit.The Best CBD Gummies for Tremors: A Comprehensive Guide to Finding Relief most terrible thing is the dragon soul. One dragon only has one dragon soul, which is more difficult to obtain than blood essence.

Even the previous secret room filled with blood symbols was not spared, and only the black giant cauldron fell into CBD Clinic Pain Relief Reviews: A Comprehensive Analysis of Topical Analgesics for Effective Pain Management (efQwg) the ruins Discover Kelly Clarkson’s Weight Loss Gummies Secret: Top Tips for One Week Before Christmas of the pit.Jiang Yuebai put all Jixiang and Jixiang s leftover food into the nest between him and the chipmunk.

I m worried that after I go Top 7 Ways Kevin James Achieved His Remarkable Weight Loss Transformation Before Christmas out this time, I ll be in debt again.This time Ling Guanghan took the initiative to walk Gunna Weight Loss 2025: How 100 Fans Embraced a Healthier Lifestyle Following His Lead up to Lu Nazhi.

There are several flower vines twining around it, blooming small colorful flowers, attracting butterflies to fly around the antlers.The baby s breath is weak and its outline is blurred.

Wen Miao saw the expressions of the three people in her eyes and knew that they were all thoughtful children.in this way, the foundation of the Xie family can be stable By the way, last time you said you chose the place where you would transform into a god to overcome the tribulation, where is it It s north of Beihai.

Is he this person Bai Jiuyou squatted beside him and tilted his head to look carefully.Anan, don t move yet Jiang Yuebai The Benefits of Spring Valley Adult Gummy Zinc: A Comprehensive Guide to Immune System Support (lIaxI) had a scarlet silk robe on his body.

What should I do with this cauldron Jiang Yuebai asked.The second thunder wave struck, and the Four Elephants and Bagua array was completely shattered.

Zhao Fuyi glanced at the direction where Jiang Yuebai was crossing the tribulation.Master Miaoyin in the sect wanted to show off in front of Miaoyin, but Ling Guanghan was number one on the Golden Core stage battle list at that time.

After seeing the token, Dongfang Yu checked the jade slips, which indeed recorded the area of each peak s spiritual fields, the type, quantity, maturity period, etc.Even the ancient banyan old demon s magic inheritance and rattan bracelet were Protein Shake Recipes for Weight Loss: Boost Your Fitness Journey with Delicious and Nutritious Shakes far inferior to this thing.

He once served as the attendant of the Qingqiu Sacred Tree.Jiang Yuebai broke the news. When Yunchong held it in his hand, it felt better than the one before Big Dog Thief.

Lu Nazhi was covered in Enhancing Male Health with Play Male Enhancement Gummy: A Comprehensive Guide (eSbMk) cold demonic aura, which turned into ice crystals and followed Do CBD Gummies Have Sugar in Them: Separating Fact from Fiction (gKKDV) him like a shadow.Zong Lie shouted loudly, and raised the heavy hammer in his hand high, rising in the wind, like a violently erupting volcano, and smashed down on one of the ice walls of the sword array.

In a big world like Qinglong Realm, there are only two types of high grade spiritual stones and top grade spiritual stones that can be traded and circulated.After Huntian s death, this place became their territory.

Xie Real User Experiences with Keto Gummies for Weight Loss: An Honest Discussion Jingshan handed over a pill. The Ganlin pill used by Yuanying monks can quickly restore spiritual energy and consciousness Does Keto Pills Work? A Florida Seniors’ Perspective After 2 Months after eating it.What about Yin Qi Yin Qi does not have demonic energy.

I can t directly penetrate the magic mist around Xingchou for the time being, but when I seriously injured her on the city wall, I secretly cast a parasitic spell on her body.Jiang Yuebai s eyes widened as he watched the Why Action Bronson Weight Loss Transformation is Inspiring Millions water snake smash through the dragon gate and pass under the gradually shattering glass archway.

He shook his hand and said, Brisbane’s Golo Weight Loss Stories: Spring 2025 Highlights I have been in the Shura Realm for almost four hundred years, and my hands are already stained with blood.Inside are pairs of spiritual The Benefits and Effects of Kanna CBD Gummies: A Comprehensive Guide (fIZLI) beasts, living leisurely lives with their respective cubs.

Gua The sky swallowing frog is waiting for the opportunity to move, and the green armored queen bee is dead In the southern part of the Demonic Domain, Lanruo The Benefits and Effectiveness of Reagan CBD Gummies for Relaxation and Wellness (SzlDx) Valley.Jiang Yuebai looked for those spiritual thoughts and saw a blue lake like a mirror.

The water lily was blocked by lots of lotus roots and was not injured.Jiang Yuebai glanced at Xiao Lu, who turned pink, rushed into the mountain wall and disappeared.

Two bloody wings appeared instantly behind Shen Huaixi, and the package moved forward.No problem, just put the Ice Beetle King and the Ice Soul Pearl into the small world, pick up the folding fan and check it out.

After looking at the cultivation data panel, he found that the bloodline column had disappeared and there were two changes in the spiritual root column.Yin and Yang are above the Five Elements, and the power of Yin Thunder is stronger than the power of the Five Elements.

However, seeing her appear, Xie Jingshan The Benefits and Effectiveness of Pure Cana CBD Gummies: A Comprehensive Review (kfbAY) was so frightened that he panicked and fell into the pool.

Boom boom boom The black and white dragon exploded, a loud noise shot into the sky, and the seawater evaporated, leaving only a terrifying pit like a ruin.It was so shameless. She stretched out a hand in front of Su Xiaoxiao.

Lu Nazhi relied on the characteristics of water to continuously absorb Zong Lie s power.It was obvious New Year, New You: Kevin James Weight Loss Journey and Tips for 2025 that the sword calamus bushes were exactly the same as those around her, and she didn t notice the aura of the grass dragon, but they were as hard as an iron wall.

This way he got a large amount of spiritual stones, so that he could concentrate on training without worrying about training resources.He originally wanted to go to the West Sea, but Zheng Yougong said The western area of Qinglong Realm is bounded by the Fulong Mountains, and outsiders cannot enter.

He finally did a good Unbiased Weight Loss Gummy Reviews: Does Keto Life Gummies Really Work? A Comprehensive Guide thing I m Best Peptide Solutions for Weight Loss: Expert Insights Two Weeks Before Christmas telling you, Brother Zhuo, Jiang Yuebai has no heart.However, Song Zhiang s spiritual roots were in conflict, and the process of forming the elixir was extremely dangerous and he almost died.

To show your authority to the entire foreign country, are you going to The Benefits and Uses of Hemp Gummies Français: A Comprehensive Guide (RUYRA) wait for the old man to commit suicide in person Or do you mean that you know that others are using you, but you are still willing to be used Wait until they have finished using you, and then throw you away like garbage.Do you know that I haven t Exploring the World of CBD Gummies in Texas: A Comprehensive Guide to CBD Gummies Texas been poisoned by the Wangyou Pill Xie Jingshan walked up to Shen Huaixi, sat down carelessly, and sniffed.

Since Miaoyin and his two disciples died one after another, it has Charlotte's Web Hemp Extract-Infused Gummies Sleep: A Comprehensive Guide to Restful Nights (fnfQC) been difficult for Ling Guanghan to get along with other disciples Fastest Diet Pills That Work: Efficacy and Safety Considerations for Rapid Weight Loss like the master disciple pair of Li Jiuchuan and Jiang Yuebai.Senior Miaoyin, are you sure that the secret passage can enter the city smoothly Miaoyin nodded, Activlife Keto Gummies: The 2025 Game-Changer for 50 American Weight Loss Warriors Before Blood River City was occupied, I walked through that secret passage many times.

I know you want to go to the West The Benefits of Dream Water Sleep Gummies for a Restful Night's Sleep (kwkBQ) Sea, and Ao Juan is your old CBD Gummies for Diabetics Canada: A Comprehensive Guide to Natural Blood Sugar Management (nXaoy) friend.Spell Secret Technique Five Thunder Methods Level 4 7.

Amidst the dragon roars one after another, the two Yuanying monks climbed up from Enhancing Male Arousal with CBD Gummies: A Comprehensive Guide to Improved Intimacy (TZKNS) the sea and immediately ran for their lives.Her spiritual energy turned The Jennifer Hudson Weight Loss Plan: A Comprehensive Guide into a heavy Say Goodbye To Midday Slumps: CBD Gummies For Sustained Energy hammer and she smashed at Tianyou Discover the Power of CBD Gummies Aphrodisiac for Enhanced Intimacy crazily.

While hunting monsters, I was attacked by the colorful ringed cuttlefish king hiding under the sea.Shen Huaixi said that this place was once the territory of the fire demon Chi Nu.

The timing of Fengyunhui must have been specially chosen by Fang Ruyan, because only at this time, the earth s spiritual energy will be consumed by the secret realm, Finding Relief with Indica Gummies for Sleep Reddit: A Comprehensive Guide (DiJiR) and Fang s protective formation will be weakened.To be on the safe side, we decided to split up. He followed the old man from his old soul line through the secret passage.

If you encounter someone you can t beat in the future, hide in the coffin and then use the coffin to escape.Qi Siheng glanced at him casually, and Jing Chujun s spiritual energy froze instantly.

As soon as Zong Lie s heavy hammer hit one of the sword beams, it was crushed into powder by the force Gummies for Diabetes: A Comprehensive Guide to Managing Blood Sugar Levels (uzAtt) accumulated Say Hello to a Better Mood with Hello Mood CBD Gummies: A Comprehensive Guide in the sword beam, and that force was very familiar to him.White feathers exploded in the sword light that filled the sky.

My master, Lord Guanghan Sword Lord and Lord Canghuo should be arriving soon.Also, I want to make a few requests. It s all for me to Understanding Bloom CBD Gummies Ingredients mature faster and better.

He once served as the attendant of the Qingqiu Sacred Tree.Don t worry Jiang Yuebai stepped out of the wooden box and looked at Zhao Fuyi with a smile.

Please be careful Speak The last two words were 2025 Diet Trend: How Vista Keto ACV Gummies Help Seniors Safely Lose 15 Pounds sandwiched between Ling Guanghan s cold and sharp Truths and Lies About Using Apple Cider Vinegar for Weight Loss: A 2025 Comprehensive Guide sword intent.Tian Nanxing glanced at Shen Huaixi in the distance, his eyes flashed slightly, and he turned away.

The flames scattered around seemed to be alive, beating in groups and returning to the black dog in front of everyone.Make a green light hit the mirror. Jiang Yuebai urged the Shu Zi Jue, and actually successfully Alive Multivitamin Gummies for Adults: A Comprehensive Guide to Boosting Overall Health and Wellness (QlFjq) absorbed the tree dragon into it.

The fog obstructed her, and when she really saw the outside, she felt as if she had been struck by lightning, dumbfounded.To enter here, you need the essence and blood of Nine Dragons to break the restriction.

It swung its body wildly, hit the formation, and roared.If she succeeds, with one palm strike, she can ideally unleash hundreds of powerful demon suppressing energy, plundering the opponent s energy and blood, leaving a trail of blood poison, and continuously destroying the opponent s body.

Well The dragon s head was choked, its roar stopped, and it swallowed Yunzhi with a gulp.They howled and fell from the mid air, stirring up dust all over the sky.

He didn t really want to fight us. But it s really annoying Once a month, you can t guard against it Someone pretends to be an errand boy from the Internal Affairs Hall, sneaks in with the vegetable cart, and someone Soul CBD Gummies Reviews 2025: Benefits, Ingredients & User Experiences (OgiXS) disguises himself Unisom Sleep Gummies Reviews: A Comprehensive Guide to Better Sleep (fNRXU) as Junior Brother Xie.He raised his head and spit out a mouthful of blood.

The Snake Willow is almost 700 years old and has not yet transformed.The black fire in your body is the earth centered demonic flame treasured by the Blood Sea Ancestor.

A large group of vampire bats the size of babies flew out of the mountains, covering the Best CBD Gummies in Columbia, SC - Top Stores and Reviews sky and the sun, and attacked the crowd gathered below.When we get to the foreign country, we won t be so anxious.

He guarded the gate of Tianjian Peak alone and fought four battles before losing.Jiang Yuebai was caught off guard and was stepped on by a deer s hoof.

On it was a woman in white clothes and red armor, holding a spear, with a heroic appearance and awe inspiring immortality.His vision blurred, and a lot of air rushed into his nose, and he arrived at a familiar place Transform Your Body with Dr. Jen Ashton Keto Gummies: A Comprehensive Review of the Ultimate Weight again.

Lu Nazhi, Euphoria Green CBD Gummies Shark Tank: The Ultimate Stress Relief Solution I m going to tear you alive to avenge Mingyi Fang Mingxin shouted loudly and hit Lu Nazhi hard with both hammers.The sky was dark and the earth was dark, and there were many strange bronze fragments floating around.

The dragon goes Comprehensive Peak CBD Gummies Reviews: Uncovering the Benefits and Effectiveness of CBD (WSvft) out to sea Jiang Yuebai stabbed with a spear, and in the moment of space, he pulled out a series of afterimages, and rushed in front of Fang Yuxing.But now, the nameless magic formula on this tripod can solve Lu Nanzhi s urgent The Benefits and Uses of CBD Anytime Gummies for Relaxation and Wellness (QRnRK) need.

Jiang Yuebai said, Okay, Master, can you find True Lord Fuyi in Mary Ruth's Sleep Gummies Melatonin Free: A Natural Solution for Restful Sleep (DCwUL) Tianshu Realm You left a message.We need to be nurtured with extra precision and care in order to exert the strongest medicinal power.

The information obtained by Hongyan Tower It was said that Master Fufeng led people from different countries to do it.Three years is a blink of an eye for a senior monk.

Arisaema is a member of the Lancao clan, and I suddenly felt a little worried about the contract with him.Make an empty space. After that, Xiao Lu and Five Ghosts were put on alert, and they quickly used little magic to help Lu Nanzhi treat his wounds.

It was a pity that Master Fuyi did not have an earth magic weapon on him.The moment it touched the golden light, Jiang Yuebai immediately saw Something familiar to her.

As long as it is properly arranged, there is no way to get in or out unless you fly in.They stretched their heads to observe the tree carefully, and from time to time they wrote on the paper with a brush.

When the mother insect dies, her soul will also perish.Opposite was the Iron Cut Straight stall. There was no one in line at the moment.

He saw a six or seven year old bald man wearing shabby gray blue monk clothes and carrying a bamboo hat on his back.Jiang Yuebai Fang Yuxing s angry shout came from behind, and Jiang Yuebai turned around with the corners of his lips raised.

As soon as he opened the The Benefits of Free Sample CBD Gummies: A Comprehensive Guide (EiWcG) door, Jiang Yuebai ran into Ding Lanzhi.Greed is the root of evil in human nature, including your parents.

Wen Miao frowned, Then you really don t regret it Best 6 Food and Exercise Tips to Lose Weight for College Students at all Lu Nazhi nodded slowly, If you don t regret it, the revenge for killing my father is not me reading more Taoist scriptures , I can just let it go by comforting myself.The little thief s gun once transformed into a green dragon.

Granny Shi Lan patted the round stool beside her. Heka from the village came to talk to her Improving Sleep Quality with His and Hers Sleep Gummies: A Comprehensive Guide (Hzorg) every day.Anyway, Jixiang can eat anything. After practicing Plenity Weight Loss: Revolutionize Your Journey to a Healthier You this technique, it just eats, absorbs and refines the power that it can absorb, and pulls out the power that cannot be absorbed In the future, if one can refine the two qi of yin and yang from the mixed power, then one will be able to transcend the Five Elements and have an even greater ability to break formations.

There are layers of space within each Debunking Myths: Can You Lose Weight with Apple Cider Vinegar? other. With her current strength, she cannot directly penetrate these three layers of space to escape.Only by reaching the level of subtle control can we create complex vortices inside the Little Demon Pill, stabilize the vortex Best CBD Melatonin Gummies for Sleep: Benefits, Effects, and Reviews in the process of Shed Pounds Safely and Swiftly: The Science Behind Eli Lilly’s Remarkable Weight Loss Drug separating the turbid air, and adjust its own aura and vortex speed at any time according to internal changes.

The entire Hades Sea turned into an ice sheet overnight, and the adjacent white water area to the east was covered with black snow for three consecutive months.The only thing that is not going well is Master s research court in Wanfa Hall.

The flame is dark red and contains evil spirits. The flames penetrated all pervasively and counterattacked upwards.The small restraints he taught her were relatively simple auxiliary restraints, hiding the powerful ones.

No one is allowed to approach, otherwise they really want to go there Revolutionize Your Weight Loss Journey with Keto ACV Gummies 500mg: A Game-Changing Supplement for a and see them.Mu Linfeng s cultivation was low, and his internal organs were immediately ruptured.

Bai Jiuyou s fear of the natural disaster did not come from Jiang Yuebai, but was engraved in the bones and blood of this body, making it difficult for her to muster the courage to resist.Xie Jingshan was still kneeling, with a complicated expression on his face, Grandpa, can you still transform into a god Xie Tianbao smiled kindly, Funky Farms CBD Extracts Boca Raton Reviews: A Comprehensive Guide to CBD Products (XXpxb) Do you know you care about grandpa Don t worry, I am also a person who has seen strong winds and waves.

I ll come back to deal with you in two days With a ruthless attitude, he ran away simply.If she tried to stack up to sixty four formations, she would be suppressed by the power of the forbidden barrier.

The Shanhai Tower did not open the door, so Jiang Yuebai returned without success.He didn t mean to harm me. He also said Xie Jingshan didn t dare to say the next thing. The old blind man said, he If Jiang Yuebai is not killed, he will definitely be killed by Jiang Yuebai in the future, just like Lu Xingyun had the intention to kill Zhufeng Sword Master for the sake of Understanding the Benefits and Effectiveness of Truth CBD Gummies the road, those who pursue the top of the road are heartless and ruthless.

Ouch Jiang Yuebai continued to be immersed in the restraint and said softly Kill yourself if you yell again.The data is recorded. It ensures that she can exert the strongest effect of Chaos Qi in the future, so that the The Benefits and Effects of 25 mg CBD Isolate Gummies: A Comprehensive Guide (nvihy) acquired Chaos Body she has risked her life for will not be wasted.

The Five Ghost Blood Escape Technique allows Jiang Yuebai to escape Biogreen CBD Blood Sugar Gummies - Natural Support for Healthy Blood Sugar Levels thousands of miles away.The three major sword sects in the Yaoguang Realm have rules.

Jiang Yuebai lay on the table and sighed. After a while, he regained his composure, took out the jade slip that recorded Dragon God Transformation , and looked at the first floor again.The battle between Void Refining monks is so terrifying Not only were they unable to resist, even Poyun Chong was hit and shattered by the aftermath when they rushed into this small world.

Although Jiang Yuebai s aura was only in the late stage of foundation building, their mastery and empty rules have always been to come quietly and leave quietly.Do you recognize it now Xie Jingshan stood up and shook off the dirt on his hands, The one in the Windhoof team Yu Qing er nodded, It s me.

Can t grasp it, can t touch it. Ouch The roar of the dragon shook, and the nine dragons on the cauldron took off and crashed into the cauldron.